Experiment: Hildebrandt Ruiz Lab_20170624_ISOPRENE_Chlorine radical_Ammonium sulfate_Low NOx_dry

Experiment

Name: Hildebrandt Ruiz Lab_20170624_ISOPRENE_Chlorine radical_Ammonium sulfate_Low NOx_dry
Date: 2017-06-24

Organization
Hildebrandt Ruiz Lab

Chamber
LHR Chamber

Experiment Set
Isoprene + Cl

Goals
To investigate gas and particle phase compounds and SOA yields.

Summary
100 ppb of Cl2 was injected and reacted with 4uL of isoprene at low RH in the presence of ammonium sulfate seeds.

Additional Notes
Experimental timeline to be acquired from previous student.

Experiment Details

Categories:

  • Gas phase chemical reaction
  • Volatility and partitioning
  • Aerosol formation
Temperature: 25
Relative Humidity: 0
Seeded Experiment: Yes
Type of Seed: Ammonium sulfate
Initial Seed Concentration Value:
Seed Concentration Units:
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 0
Reaction type:
Oxidant Name: Chlorine radical
Initial Oxidant Concentration Value: 100 (parts_per_billion)
RO2 Main Fate: Not Sure
RO2 Lifetime: (Seconds)
Pressure:

Data Sets

ID Instrument File  
258 NOx monitor 2017_06_24_Iso_Chl_NOx_monitor.csv
259 O3 monitor 2017_06_24_O3_monitor.csv
260 CAPS NO2 monitor 2017_06_24_NO2.csv
261 SEMS 2017_06_24_SEMS_avg_dist.csv
262 SEMS 2017_06_24_SEMS_total_conc.csv

Data Set plots
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Experiment Set Details

Name: Isoprene + Cl
Time format and units:
Description:
Environmental chamber experiments were carried out under low-NOx conditions with isoprene and chlorine as primary VOC and oxidant sources. Secondary organic aerosol yields were calculated upon complete isoprene consumption. Formation of particulate organochloride was tracked using an ACSM. A high-resolution time-of-flight chemical ionization mass spectrometer was used to determine the molecular composition of gas-phase species using iodide–water and hydronium–water cluster ionization.

Collaborators:

  • Dongyu S. Wang University of Texas at Austin, now at Paul Scherrer Institute in Switzerland
  • Lea Hildebrandt Ruiz University of Texas at Austin

Download

Download this Experiment (85.07 KB)

Contacts

Principal investigator:

Lea Hildebrandt Ruiz
E-mail: lhr@che.utexas.edu
OrcID: 0000-0001-8378-1882

Data Manager:

Lea Hildebrandt Ruiz
E-mail: lhr@che.utexas.edu

Reactant

Reactant Compound type Concentration Concentration units
ISOPRENE (6557) 98 Parts Per Billion

Timeline

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Citations
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Characterizations
Light Flux Characterizations:
(None)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
(None)

Chamber Details

Name: LHR Chamber
Volume in cubic meters: 8.92
Shape: Rectangular Prism
Surface area in cubic meters: 26.4
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 5.0
Replacement date: 2018-06-15
Replacement frequency: As needed
Cleaning method: Flushing with air Flushing with air with UV lights on Oxidation
o3 background:
nox background:
Particle background in micrograms per cubic meter: < 10 counts/cm3
Air filtration method: NA
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 5
Temparature range (max degrees celcius): 50
Humidity Control: No
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 0
Relative humidity range (max percent): 85
Particle experiment capability: 1
Lights: Yes
Light source type(s): UV-A Blacklight
Supplemental information:
Additional Notes: