Experiment: Hildebrandt Ruiz Lab_20170708_ISOPRENE_Chlorine radical_Ammonium sulfate + Sulfuric acid_C7_continuous Cl injection_acidic seed

Experiment

Name: Hildebrandt Ruiz Lab_20170708_ISOPRENE_Chlorine radical_Ammonium sulfate + Sulfuric acid_C7_continuous Cl injection_acidic seed
Date: 2017-07-08

Organization
Hildebrandt Ruiz Lab

Chamber
LHR Chamber

Experiment Set
Isoprene + Cl

Goals
To calculate SOA yield from Cl-initiated photo-oxidation of isoprene at a VOC:Cl2 ratio of 0.80, and using acidic seed. Cl2 was injected continuously during lights-on period.

Summary
Acidic seed was injected with an initial seed surface area of 3200 um2/cm3, followed by a continuous Cl2 injection out of a gas cylinder, and the isoprene injection using a heated glass bulb. Temperature was kept at 25C for the whole duration of the experiment, while RH was kept at less than 10%.

Experiment Details

Categories:

  • Gas phase chemical reaction
  • Volatility and partitioning
  • Aerosol formation
Temperature: 25
Relative Humidity: 0
Seeded Experiment: Yes
Type of Seed: Ammonium sulfate + Sulfuric acid
Initial Seed Concentration Value: 3200
Seed Concentration Units:
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 0
Reaction type:
Oxidant Name: Chlorine radical
Initial Oxidant Concentration Value: 150 (parts_per_billion)
RO2 Main Fate: Not Sure
RO2 Lifetime: (Seconds)
Pressure:

Data Sets

ID Instrument File  
1045 CAPS NO2 monitor C7_2017_07_08_CAPSNO2.csv
1046 Labview C7_2017_07_08_Labview.csv

Data Set plots
Choose a file: Choose the X-Axis:

Experiment Set Details

Name: Isoprene + Cl
Time format and units:
Description:
Environmental chamber experiments were carried out under low-NOx conditions with isoprene and chlorine as primary VOC and oxidant sources. Secondary organic aerosol yields were calculated upon complete isoprene consumption. Formation of particulate organochloride was tracked using an ACSM. A high-resolution time-of-flight chemical ionization mass spectrometer was used to determine the molecular composition of gas-phase species using iodide–water and hydronium–water cluster ionization.

Collaborators:

  • Dongyu S. Wang University of Texas at Austin, now at Paul Scherrer Institute in Switzerland
  • Lea Hildebrandt Ruiz University of Texas at Austin

Download

Download this Experiment (85.38 KB)

Contacts

Principal investigator:

Lea Hildebrandt Ruiz
E-mail: lhr@che.utexas.edu
OrcID: 0000-0001-8378-1882

Data Manager:

Lea Hildebrandt Ruiz
E-mail: lhr@che.utexas.edu

Reactant

Reactant Compound type Concentration Concentration units
ISOPRENE (6557) 120 Parts Per Billion

C7_timeline.csv Timeline

Time (HH:MM) Event description
9:52 FIGAERO Blank
9:57 Adjusting IMR pressure controller settings
10:18 Adjusting IMR pressure controller setting
10:55 Acquisition aborted after 20 complete writes. 3 additional bufs in the incomplete last write.
10:58 Samplign chamber air
11:05 Set up injection line; ready to start injecting isoprene
11:08 Injecting 5 ul isoprene, 2 LPM Clean air assist
11:45 UV on, starting 0.1 LPM Cl2 injection with 0.9 LPM assist
14:17 Cl2 Off
15:02 UV off (0/5
15:51 prepare to start FIGAERO collection
15:51 Acquisition aborted after 134 complete writes. 5 additional bufs in the incomplete last write.

Citations
Cite this experiment: Publication associated with this experiment:

Characterizations
Light Flux Characterizations:
(None)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
(None)

Chamber Details

Name: LHR Chamber
Volume in cubic meters: 8.92
Shape: Rectangular Prism
Surface area in cubic meters: 26.4
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 5.0
Replacement date: 2018-06-15
Replacement frequency: As needed
Cleaning method: Flushing with air Flushing with air with UV lights on Oxidation
o3 background:
nox background:
Particle background in micrograms per cubic meter: < 10 counts/cm3
Air filtration method: NA
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 5
Temparature range (max degrees celcius): 50
Humidity Control: No
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 0
Relative humidity range (max percent): 85
Particle experiment capability: 1
Lights: Yes
Light source type(s): UV-A Blacklight
Supplemental information:
Additional Notes: