Instrument - Gas chromatograph with flame ionization detector
Short name:
GC-FID
Full name:
Gas chromatograph with flame ionization detector
What is being measured:
Sampling Protocol:
Online
Manufacturer:
Agilent
Model:
6890N
Instrument year
:
None specified
Data recording software:
Chemstation
Data analysis software:
Chemstation
Raw data time resolution:
Approximately 15-16 minutes per run
Analysis data averaging:
None
Detection limit:
1 - 2 ppb
Sensitivity to temperature (and correction method, if applicable):
:
None noted
Sensitivity to relative humidity (and correction method, if applicable):
:
None noted
Sampling method:
Directly connected to chamber, gas sampling with 6 way pneumatically operated valve
Sample preparation method:
None
Sample residence time (chamber to instrument) (seconds):
Length of tubing (cm):
0.02
Instrument flow rate:
0.5
Tubing inner diameter:
Tubing material:
FEP Teflon
Chemical identification method:
Chemicals are identified by their retention time in the method, as calibrated by standards
Data analysis method:
Peaks are integrated manually in Chemstation
Quantification method:
Integrated peak areas are divided by a calibration factor, as determined by calibration with authentic standards
Calibration method:
For each analyte, a concentration calibration is performed by introducing a known volume of the analyte to a 100L "pillow bag" at concentrations around 20-200 ppb. Generally, a concentrated "stock" is created and diluted, and the concentration of the stock is checked with FT-IR when appropriate. Several runs at each concentration are performed to get a standard deviation.
Calibration drift estimate:
Low (on the order of weeks)
Calibration schedule:
before experiments
Uncertainty estimation method:
Uncertainties are estimated based on the errors that may occur from the dilution process of making calibration bags.
Known interferences:
ISOPOOH, IEPOX, and some IHNs decompose to form Methacrolein and MVK in the GC-FID. Cold-trapping is used when interferences are anticipated.
Link to supplemental information:
Paper that describes interferences. https://agupubs.onlinelibrary.wiley.com/doi/full/10.1002/2014GL061919
Additional notes:
Measurement uncertainty:
Measurement units: