Particle Loss Characterization #27 - 2020-09-21
ID:
27
Name:
Ammonium sulfate
Instrument:
scanning mobility particle sizer (#484)
Chamber:
Tran's big bag of air
Temperature (°C):
22
Relative humidity (%):
5
Particle composition:
- Ammonium sulfate
Particle measurement size range:
14 - 670 nm
Particle generation method:
Atomization of 0.06 M ammonium sulfate solution
Date of characterization experiment:
2020-09-21
Months since calibration:
Wall loss experiment description:
H2O2 and O3 were injected concurrent with ammonium sulfate atomization, to mimic the a-pinene ozonolysis experiments. After injections the chamber was briefly mixed with pulses of air and allowed to sit undisturbed for 6.5 hours.
Wall loss rates calculation method:
The loss of each particle size was binned in Matlab and an exponential fit was performed to extract the first order loss in per minute.
Frequency of particle loss experiments:
As needed for particle type and RH (doesn't change much)
Wall loss correction description:
SMPS data from SOA experiments select the particle loss file that closely match the particle type (pure organic, pure AS, mixed AS/org, or other) and then each size bin is corrected for the loss frequency. We check that the ~ 1 hour period that the particles equilibrate in the chamber prior to experiment start is corrected to zero loss (flat line) from the appropriate wall loss file.
Link to supplemental information:
Additional notes:
Characterization data file:
Wall_loss_200921_AS_dry.csv
Experiments
ID | Name | Start date | Experiment Category | Reaction Type | Reactant(s) | Oxidant Name | Temperature | Humidity | Type of Seed | RO2 Main Fate | Data Sets (count) | Actions |
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