Experiment: Caltech Atmospheric Chamber_20130415_trans-beta IEPOX/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate_AqueousPhotooxidation

Experiment

Name: Caltech Atmospheric Chamber_20130415_trans-beta IEPOX/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate_AqueousPhotooxidation
Date: 2013-04-15

Organization
Caltech Atmospheric Chamber

Chamber
Near/Far Bag 2012-2015 (Tran)

Experiment Set
IEPOX uptake experiments

Goals
This is similar to the 130410 experiment except that H2O2 is atomized with ammonium sulfate in the particles. IEPOX was introduced to hydrated ammonium sulfate at 50% RH, the chamber was cooled to to remove the IEPOX from the gas phase (no more traces in CIMS); this increased the RH to ~80%) then lights turned on to photolyze the IEPOX on the particles.

Summary
Gaseous H2O2 was not observed when the H2O2 was atomized with AS in the particle, which suggests all the reaction was in the particle phase. The organic aerosol as seen on AMS reacted nearly all away. Fragmentation products such as hydroxyacetone, glycolaldehyde, formic acid, acetic acid, and peroxyacetic acid were seen as products on CIMS

Additional Notes
Note that this experiment needs a chamber blank to subtract out the gas phase oxygenated voc formation from the walls.

Experiment Details

Categories:

  • Condensed-phase chemical reaction
  • Multiphase chemical reaction
Temperature: 16-22
Relative Humidity: 49-80
Seeded Experiment: Yes
Type of Seed: Ammonium sulfate
Initial Seed Concentration Value: 100
Seed Concentration Units: micrograms_per_cubic_meter
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 49-80
Reaction type:
Oxidant Name: Hydroxyl radical
Initial Oxidant Concentration Value: 1.5e6 (parts_per_billion)
RO2 Main Fate: HO2
RO2 Lifetime: (Seconds)
Pressure: 750 Torr

Data Sets

ID Instrument File  
3513 CIMS 130415_CIMS.csv
3514 HR-ToF-AMS 130415_ams.csv
3515 O3NOxTRH 130415_gas_analyzers.csv

Data Set plots
Choose a file: Choose the X-Axis:

Experiment Set Details

Name: IEPOX uptake experiments
Time format and units: Experiment time (minutes, local)
Description:
Reactive uptake of cis and trans beta-IEPOX (isoprene epoxydiols with the epoxide in the 2-position, and the -CH2OH in the cis and trans conformations) onto dry and hydrated seeds of ammonium sulfate (AS), as well as other inorganic seeds. Note that wall loss is already applied to AMS particle data.

Collaborators:

  • Tran B Nguyen UC Davis
  • Paul O Wennberg Caltech

Download

Download this Experiment (60.84 KB)

Contacts

Principal investigator:

John H Seinfeld
Phone: (626) 395-4635
E-mail: seinfeld@caltech.edu
OrcID: https://orcid.org/0000-0003-1344-4068

Data Manager:

Stephanie Kong
Phone: 626-395-3194
E-mail: wkong@caltech.edu

Reactants

Reactant Compound type Concentration Concentration units
trans-beta IEPOX 14 Parts Per Billion
hydrogen peroxide (784) 2 Parts Per Million

130415_Timeline.csv Timeline

Local time (hh:mm) Action
12:00 (time 0) Inject IEPOX from a heated (~ 65 Celsius) glass bulb (chamber is already at 80% RH and has ~ 120ug/m3 of AS seeds that was atomized WITH H2O2 in the solution)
14:30 Stop IEPOX injection (decrease chamber temperature to 16 Celsius)
18:10 Decrease temperature to 16 Celsius; chamber RH went up to 77%
18:40 Lights on 100% intensity
24:24:00 Lights off and shutdown

Citations
Cite this experiment: Publication associated with this experiment:

Characterizations
Light Flux Characterizations:
2013-12-13 (#28)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
2013-04-03 (#9)

Chamber Details

Name: Near/Far Bag 2012-2015 (Tran)
Volume in cubic meters: 27
Shape: Rectangular Prism
Surface area in cubic meters: 41.8
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 50
Replacement date:
Replacement frequency: As needed
Cleaning method: Flushing with air
o3 background: 0.5 ppb
nox background: 0.1 ppb for Near, > 0.1 ppb for Far
Particle background in micrograms per cubic meter: < 0.1 ug/m3
Air filtration method: Custom Filter
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 20
Temparature range (max degrees celcius): 45
Humidity Control: Yes
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 5
Relative humidity range (max percent): 100
Particle experiment capability: 1
Lights: Yes
Light source type(s): UVA Black Lamps
Supplemental information: https://www.worldscientific.com/doi/abs/10.1142/9789813147355_0001
Additional Notes: