Experiment Set: Branched Alkane OH, High NOx

Experiment Set: Branched Alkane OH, High NOx
Name: Branched Alkane OH, High NOx
Time format and units: Minutes from start of reaction

Organization
Ziemann

Chamber

UC Riverside (APRC)

Description
Branched alkanes were oxidized by OH radicals in a high NOx environment. For each experiment, 1 ppmv of the alkane*, 10 ppmv methyl nitrite, and 10 ppmv NO. *The only exception is heptadecane, which was run at 0.5 ppmv. The following linear alkanes were used: 3,4-diethylhexane, 2-methylundecane, 2,3-dimethyldecane, 2,6-dimethyldecane, 2,3,6,7-tetramethyloctane, 2,2,4,4-tetramethyloctane, 2,2,4,6,6-pentamethylheptane, 4,4-dipropropylheptane, 2,3,3-trimethyldecane, 2,6,10-ttrimethyldodecane, n-butylcyclohexane, and n-deccylcyclohexane.

Collaborators:
No collaborators were defined


Experiments (12)

ID Name Start date Experiment Category Reaction Type Reactant(s) Oxidant Name Temperature Humidity Type of Seed RO2 Main Fate Data Sets (count) Actions
678 Ziemann_20071119_Butylcyclohexane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-19 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation Butylcyclohexane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
679 Ziemann_20071120_3,4-Diethylhexane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-20 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 3,4-Diethylhexane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
680 Ziemann_20071121_2-Methylundecane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-21 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2-Methylundecane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
681 Ziemann_20071122_2,3-Dimethyldecane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-22 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,3-Dimethyldecane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
682 Ziemann_20071123_2,6-Dimethyldecane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-23 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,6-Dimethyldecane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
683 Ziemann_20071124_2,2,4,4-Tetramethyloctane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-24 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,2,4,4-Tetramethyloctane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
684 Ziemann_20071125_2,3,6,7-Tetramethyloctane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-25 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,3,6,7-Tetramethyloctane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
685 Ziemann_20071126_2,2,4,6,6-Pentamethylheptane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-26 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,2,4,6,6-Pentamethylheptane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
687 Ziemann_20071127_4,4-Dipropylheptane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-27 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 4,4-Dipropylheptane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
688 Ziemann_20071128_2,3,3-Trimethyldecane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-28 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,3,3-Trimethyldecane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
689 Ziemann_20071129_2,6,10-Trimethyldodecane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-29 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation 2,6,10-Trimethyldodecane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download
690 Ziemann_20071130_Decylcyclohexane/Methyl nitrite/Nitric oxide_Hydroxyl radical_DOS 2007-11-30 Gas phase chemical reaction, Photolysis, any phase, Aerosol formation, Aerosol aging Photooxidation Decylcyclohexane, Methyl nitrite, Nitric oxide Hydroxyl radical 25 1 DOS NO 1 Download