Particle Loss Characterization #29 - 2013-03-06

ID:
29

Name:
Particle Wallloss Dry

Instrument:
Soft X-ray Differential Mobility Analyzer in Negative Mode (#413)

Chamber:
Near/Far Bag 2012-2015 (Tran)

Temperature (°C):
22

Relative humidity (%):
4

Particle composition:

  • Ammonium sulfate

Particle measurement size range:
16-915 nm

Particle generation method:
Atomization

Date of characterization experiment:
2013-03-06

Months since calibration:

Wall loss experiment description:
Introduce desired amounts of relative humidity (RH). Atomize particles into the bag. Mix briefly, and monitor wall loss over the course of several hours.

Wall loss rates calculation method:
Fit each particle diameter size bin with their loss rates (s-1)

Frequency of particle loss experiments:
Usually they are done for each experiment set but the rates don't change much throughout the years

Wall loss correction description:
At each particle size bin, the loss rate is used to calculate how many particles were lost and then added back on. We check that this correct doesn't increase or decrease particle volume during times when no reaction is occuring.

Link to supplemental information:

Additional notes:

Characterization data file:
130306_particlewallloss_dry.csv


Experiments
ID Name Start date Experiment Category Reaction Type Reactant(s) Oxidant Name Temperature Humidity Type of Seed RO2 Main Fate Data Sets (count) Actions
609 Caltech Atmospheric Chamber_20140722_Methacrylolyl peroxynitrate(MPAN)/ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Dry 2014-07-22 Gas phase chemical reaction, Aerosol formation Photooxidation Methacrylolyl peroxynitrate(MPAN), ALPHA-PINENE, hydrogen peroxide Hydroxyl radical 15 4 HO2 4 Download
610 Caltech Atmospheric Chamber_20140724_Methacrylolyl peroxynitrate(MPAN)/ALPHA-PINENE/hydrogen peroxide/Methacrylic acid epoxide (MAE)_Hydroxyl radical_No Seed_Dry 2014-07-24 Gas phase chemical reaction, Aerosol formation Photooxidation Methacrylolyl peroxynitrate(MPAN), ALPHA-PINENE, hydrogen peroxide, Methacrylic acid epoxide (MAE) Hydroxyl radical 15 4 HO2 4 Download
611 Caltech Atmospheric Chamber_20140726_Methacrylolyl peroxynitrate(MPAN)/hydrogen peroxide_Hydroxyl radical_No Seed_Dry 2014-07-26 Gas phase chemical reaction, Aerosol formation Photooxidation Methacrylolyl peroxynitrate(MPAN), hydrogen peroxide Hydroxyl radical 15 4 HO2 4 Download
612 Caltech Atmospheric Chamber_20140802_Methacrylolyl peroxynitrate(MPAN)/ALPHA-PINENE/hydrogen peroxide/Methacrylic acid epoxide (MAE)_Hydroxyl radical_No Seed_Dry 2014-08-02 Gas phase chemical reaction, Aerosol formation Photooxidation Methacrylolyl peroxynitrate(MPAN), ALPHA-PINENE, hydrogen peroxide, Methacrylic acid epoxide (MAE) Hydroxyl radical 15 4 HO2 5 Download
613 Caltech Atmospheric Chamber_20140729_METHACROLEIN/hydrogen peroxide/10102-44-0_Hydroxyl radical_No Seed_Dry 2014-07-29 Gas phase chemical reaction, Aerosol formation Photooxidation METHACROLEIN, hydrogen peroxide, 10102-44-0 Hydroxyl radical 15 4 NO2 5 Download
614 Caltech Atmospheric Chamber_20140731_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_No Seed_Dry 2014-07-31 Gas phase chemical reaction, Aerosol formation Photooxidation METHACROLEIN, Methyl nitrite, 10102-44-0 Hydroxyl radical 25 4 NO2 5 Download
615 Caltech Atmospheric Chamber_20140805_Tridecane/hydrogen peroxide_Hydroxyl radical_No Seed_Dry 2014-08-05 Gas phase chemical reaction, Aerosol formation Photooxidation Tridecane, hydrogen peroxide Hydroxyl radical 15 4 HO2 4 Download
616 Caltech Atmospheric Chamber_20140807_Methacrylolyl peroxynitrate(MPAN)/hydrogen peroxide_Hydroxyl radical_No Seed_Dry 2014-08-07 Gas phase chemical reaction, Aerosol formation Photooxidation Methacrylolyl peroxynitrate(MPAN), hydrogen peroxide Hydroxyl radical 15 4 HO2 5 Download
617 Caltech Atmospheric Chamber_20140812_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_No Seed_Dry 2014-08-12 Gas phase chemical reaction, Aerosol formation Photooxidation METHACROLEIN, Methyl nitrite, 10102-44-0 Hydroxyl radical 15 4 NO2 5 Download
618 Caltech Atmospheric Chamber_20140814_ISOBUTYRALDEHYDE/Methyl nitrite/10102-44-0_Hydroxyl radical_No Seed_Dry 2014-08-14 Gas phase chemical reaction, Aerosol formation Photooxidation ISOBUTYRALDEHYDE, Methyl nitrite, 10102-44-0 Hydroxyl radical 26 4 NO2 5 Download
619 Caltech Atmospheric Chamber_20140816_2-Methyl-3-buten-1-ol/Methyl nitrite/10102-44-0/OZONE_Hydroxyl radical_No Seed_Dry 2014-08-16 Gas phase chemical reaction, Aerosol formation Photooxidation 2-Methyl-3-buten-1-ol, Methyl nitrite, 10102-44-0, OZONE Hydroxyl radical 25 4 NO2 4 Download
620 Caltech Atmospheric Chamber_20140819_METHACROLEIN/Methyl nitrite/10102-44-0_Hydroxyl radical_No Seed_Dry 2014-08-19 Gas phase chemical reaction, Aerosol formation Photooxidation METHACROLEIN, Methyl nitrite, 10102-44-0 Hydroxyl radical 25 4 NO2 5 Download