Particle Loss Characterization #38 - 2022-07-29

ID:
38

Name:
Ammonium sulfate RH 64 with NO3

Instrument:
scanning mobility particle sizer (#484)

Chamber:
Tran's big bag of air

Temperature (°C):
22

Relative humidity (%):
64

Particle composition:

  • Ammonium sulfate

Particle measurement size range:
15-700 nm

Particle generation method:
atomization of a 0.3 M ammonium sulfate solution in water using N2

Date of characterization experiment:
2022-07-29

Months since calibration:

Wall loss experiment description:
The chamber was humidified to the desired RH. Ozone (150 ppb), NO2 (50 ppb), and H2O2 (4 ppb) were injected to match nighttime chemistry experiments in the "terpene nighttime chemistry" set. Particles were injected, and briefly mixed with pulsed air. Then the SMPS monitored the loss rate over the course of several hours.

Wall loss rates calculation method:
The loss of each particle size was binned in Matlab and an exponential fit was performed to extract the first order loss in per minute.

Frequency of particle loss experiments:
As needed for particle type and RH (doesn't change much)

Wall loss correction description:
SMPS data from SOA experiments select the particle loss file that closely match the particle type (pure organic, pure AS, mixed AS/org, or other) and then each size bin is corrected for the loss frequency. We check that the ~ 1 hour period that the particles equilibrate in the chamber prior to experiment start is corrected to zero loss (flat line) from the appropriate wall loss file.

Link to supplemental information:

Additional notes:

Characterization data file:
220729_betas.csv


Experiments
ID Name Start date Experiment Category Reaction Type Reactant(s) Oxidant Name Temperature Humidity Type of Seed RO2 Main Fate Data Sets (count) Actions
870 Nguyen Group_20220520_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/alpha-Pinene_Nitrate radical_Ammonium sulfate 2022-05-20 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, alpha-Pinene Nitrate radical 22 66 Ammonium sulfate RO2 5 Download
872 Nguyen Group_20220525_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/beta-Pinene_Nitrate radical_Ammonium sulfate 2022-05-25 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, beta-Pinene Nitrate radical 22 67 Ammonium sulfate RO2 6 Download
875 Nguyen Group_20220601_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/Limonene_Nitrate radical_Ammonium sulfate 2022-06-01 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, Limonene Nitrate radical 22 63 Ammonium sulfate RO2 5 Download
877 Nguyen Group_20220613_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/(+)-3-Carene_Nitrate radical_Ammonium sulfate 2022-06-13 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, (+)-3-Carene Nitrate radical 22 64 Ammonium sulfate RO2 5 Download
879 Nguyen Group_20220614_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/gamma-Terpinene_Nitrate radical_Ammonium sulfate 2022-06-14 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, gamma-Terpinene Nitrate radical 22 65 Ammonium sulfate RO2 6 Download
881 Nguyen Group_20220715_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/Ocimene_Nitrate radical_Ammonium sulfate 2022-07-15 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, Ocimene Nitrate radical 22 65 Ammonium sulfate RO2 5 Download
883 Nguyen Group_20220706_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/Sabinene_Nitrate radical_Ammonium sulfate 2022-07-06 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, Sabinene Nitrate radical 22 63 Ammonium sulfate RO2 6 Download
885 Nguyen Group_20220708_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/Myrcene_Nitrate radical_Ammonium sulfate 2022-07-08 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, Myrcene Nitrate radical 22 62 Ammonium sulfate RO2 5 Download
887 Nguyen Group_20220624_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/Camphene_Nitrate radical_Ammonium sulfate 2022-06-24 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, Camphene Nitrate radical 22 63 Ammonium sulfate RO2 6 Download
889 Nguyen Group_20220727_Nitrogen Dioxide/Ammonium Sulfate/Ozone/Hydrogen Peroxide/2-(3-Acetyl-2,2-dimethylcyclobutyl)acetaldehyde_Nitrate radical_Ammonium sulfate 2022-07-27 Gas phase chemical reaction, Aerosol formation Dark oxidation Nitrogen Dioxide, Ammonium Sulfate (Aerosol) , Ozone, Hydrogen Peroxide, 2-(3-Acetyl-2,2-dimethylcyclobutyl)acetaldehyde Nitrate radical 22 66 Ammonium sulfate RO2 5 Download