Vapor Loss Characterization #10 - Vapor wall loss RH parameterization for HMHP, HCOOH, H2O2
Name:
Vapor wall loss RH parameterization for HMHP, HCOOH, H2O2
Instrument:
Chemical Ionization Mass Spectrometer with CF3O-
Chamber:
Near/Far Bag 2012-2015 (Tran)
Temperature (°C):
24
Relative humidity (%):
90
Volatile compound name or class:
HMHP, H2O2, HCOOH
Volatile compound source:
- In-situ formation via reaction
Date of characterization experiment:
2016-05-11
Months since calibration:
Wall loss experiment description:
HMHP, HCOOH, and H2O2 were made in the chamber at different RH and the loss observed. Then the trend with respect to RH was reported
Vapor loss calculation method:
Fitted the amount of chemical remaining with time for the loss rate in per minute
Parameterization developed:
Yes
Parameterization description:
The parameterization is a linear trend with relative humidity, after the individual loss rates were obtained, then the RH dependence was fitted using the linear least squares method
Link to supplemental information:
Additional notes:
Characterization data file:
Vapor_Wall_Loss_20160511_HCOOH_HMHP_H2O2.csv
Experiments
ID | Name | Start date | Experiment Category | Reaction Type | Reactant(s) | Oxidant Name | Temperature | Humidity | Type of Seed | RO2 Main Fate | Data Sets (count) | Actions |
---|---|---|---|---|---|---|---|---|---|---|---|---|
625 | Caltech Atmospheric Chamber_20130406_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-04-06 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
626 | Caltech Atmospheric Chamber_20130407_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-04-07 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
627 | Caltech Atmospheric Chamber_20130414_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-04-14 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
628 | Caltech Atmospheric Chamber_20130420_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-04-20 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
629 | Caltech Atmospheric Chamber_20130421_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH27 | 2013-04-21 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 27 | Not Sure | 3 | Download | |
630 | Caltech Atmospheric Chamber_20130425_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH51 | 2013-04-25 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 51 | Not Sure | 3 | Download | |
631 | Caltech Atmospheric Chamber_20130427_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH76 | 2013-04-27 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 76 | Not Sure | 3 | Download | |
632 | Caltech Atmospheric Chamber_20130429_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH13 | 2013-04-29 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 13 | Not Sure | 3 | Download | |
633 | Caltech Atmospheric Chamber_20131113_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-11-13 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
634 | Caltech Atmospheric Chamber_20131115_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH73 | 2013-11-15 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 73 | Not Sure | 3 | Download | |
635 | Caltech Atmospheric Chamber_20131116_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH44 | 2013-11-16 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 44 | Not Sure | 3 | Download | |
636 | Caltech Atmospheric Chamber_20131118_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-11-18 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
637 | Caltech Atmospheric Chamber_20140822_ISOPRENE/CYCLOHEXANE/sulfur dioxide_Ozone_No Seed_RH19 | 2014-08-22 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE, sulfur dioxide | Ozone | 24 | 19 | Not Sure | 4 | Download | |
638 | Caltech Atmospheric Chamber_20140824_ISOPRENE/CYCLOHEXANE/sulfur dioxide_Ozone_No Seed_Dry | 2014-08-24 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE, sulfur dioxide | Ozone | 24 | 3 | Not Sure | 4 | Download | |
639 | Caltech Atmospheric Chamber_20140822_ISOPRENE/CYCLOHEXANE/sulfur dioxide_Ozone_No Seed_Dry_highSO2 | 2014-08-22 | Gas phase chemical reaction | Dark oxidation | ISOPRENE, CYCLOHEXANE, sulfur dioxide | Ozone | 24 | 3 | Not Sure | 4 | Download | |
640 | Caltech Atmospheric Chamber_20131107_1,3-BUTADIENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-11-07 | Gas phase chemical reaction | Dark oxidation | 1,3-BUTADIENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download | |
641 | Caltech Atmospheric Chamber_20131109_1,3-BUTADIENE/CYCLOHEXANE_Ozone_No Seed_RH50 | 2013-11-09 | Gas phase chemical reaction | Dark oxidation | 1,3-BUTADIENE, CYCLOHEXANE | Ozone | 24 | 50 | Not Sure | 3 | Download | |
642 | Caltech Atmospheric Chamber_20131113_1,3-BUTADIENE/CYCLOHEXANE_Ozone_No Seed_Dry | 2013-11-13 | Gas phase chemical reaction | Dark oxidation | 1,3-BUTADIENE, CYCLOHEXANE | Ozone | 24 | 4 | Not Sure | 3 | Download |