Vapor Loss Characterization #10 - Vapor wall loss RH parameterization for HMHP, HCOOH, H2O2

Name:
Vapor wall loss RH parameterization for HMHP, HCOOH, H2O2

Instrument:
Chemical Ionization Mass Spectrometer with CF3O-

Chamber:
Near/Far Bag 2012-2015 (Tran)

Temperature (°C):
24

Relative humidity (%):
90

Volatile compound name or class:
HMHP, H2O2, HCOOH

Volatile compound source:

  • In-situ formation via reaction

Date of characterization experiment:
2016-05-11

Months since calibration:

Wall loss experiment description:
HMHP, HCOOH, and H2O2 were made in the chamber at different RH and the loss observed. Then the trend with respect to RH was reported

Vapor loss calculation method:
Fitted the amount of chemical remaining with time for the loss rate in per minute

Parameterization developed:
Yes

Parameterization description:
The parameterization is a linear trend with relative humidity, after the individual loss rates were obtained, then the RH dependence was fitted using the linear least squares method

Link to supplemental information:

Additional notes:

Characterization data file:
Vapor_Wall_Loss_20160511_HCOOH_HMHP_H2O2.csv


Experiments
ID Name Start date Experiment Category Reaction Type Reactant(s) Oxidant Name Temperature Humidity Type of Seed RO2 Main Fate Data Sets (count) Actions
625 Caltech Atmospheric Chamber_20130406_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-04-06 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
626 Caltech Atmospheric Chamber_20130407_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-04-07 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
627 Caltech Atmospheric Chamber_20130414_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-04-14 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
628 Caltech Atmospheric Chamber_20130420_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-04-20 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
629 Caltech Atmospheric Chamber_20130421_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH27 2013-04-21 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 27 Not Sure 3 Download
630 Caltech Atmospheric Chamber_20130425_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH51 2013-04-25 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 51 Not Sure 3 Download
631 Caltech Atmospheric Chamber_20130427_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH76 2013-04-27 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 76 Not Sure 3 Download
632 Caltech Atmospheric Chamber_20130429_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH13 2013-04-29 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 13 Not Sure 3 Download
633 Caltech Atmospheric Chamber_20131113_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-11-13 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
634 Caltech Atmospheric Chamber_20131115_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH73 2013-11-15 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 73 Not Sure 3 Download
635 Caltech Atmospheric Chamber_20131116_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_RH44 2013-11-16 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 44 Not Sure 3 Download
636 Caltech Atmospheric Chamber_20131118_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-11-18 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
637 Caltech Atmospheric Chamber_20140822_ISOPRENE/CYCLOHEXANE/sulfur dioxide_Ozone_No Seed_RH19 2014-08-22 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE, sulfur dioxide Ozone 24 19 Not Sure 4 Download
638 Caltech Atmospheric Chamber_20140824_ISOPRENE/CYCLOHEXANE/sulfur dioxide_Ozone_No Seed_Dry 2014-08-24 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE, sulfur dioxide Ozone 24 3 Not Sure 4 Download
639 Caltech Atmospheric Chamber_20140822_ISOPRENE/CYCLOHEXANE/sulfur dioxide_Ozone_No Seed_Dry_highSO2 2014-08-22 Gas phase chemical reaction Dark oxidation ISOPRENE, CYCLOHEXANE, sulfur dioxide Ozone 24 3 Not Sure 4 Download
640 Caltech Atmospheric Chamber_20131107_1,3-BUTADIENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-11-07 Gas phase chemical reaction Dark oxidation 1,3-BUTADIENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download
641 Caltech Atmospheric Chamber_20131109_1,3-BUTADIENE/CYCLOHEXANE_Ozone_No Seed_RH50 2013-11-09 Gas phase chemical reaction Dark oxidation 1,3-BUTADIENE, CYCLOHEXANE Ozone 24 50 Not Sure 3 Download
642 Caltech Atmospheric Chamber_20131113_1,3-BUTADIENE/CYCLOHEXANE_Ozone_No Seed_Dry 2013-11-13 Gas phase chemical reaction Dark oxidation 1,3-BUTADIENE, CYCLOHEXANE Ozone 24 4 Not Sure 3 Download