Experiment: UCR-CECERT-APL-Cocker Group_20161009_NOx/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2260B - Weihua

Experiment

Name: UCR-CECERT-APL-Cocker Group_20161009_NOx/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2260B - Weihua
Date: 2016-10-09

Organization
UCR-CECERT-APL-Cocker Group

Chamber
EPA chamber

Experiment Set
Weihua Li Experiments

Goals
Diesel photo-oxidation under NOx and SOA surrogate -- Control

Summary
1.1ppmc surrogate +25ppb NOx +1ppmc H2O2 INSTRUMENTS: AMS, SMPS, GC1

Additional Notes
GC1 was not working until 10:44 AM, did not get the first point.

Experiment Details

Categories:

  • Photolysis, any phase
  • Blank/Control
Temperature: 28
Relative Humidity: 0.01
Seeded Experiment: No
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 0.01
Reaction type:
Oxidant Name: Hydroxyl radical
Initial Oxidant Concentration Value: N/A (molecules_per_cubic_centimeter)
RO2 Main Fate: NO
RO2 Lifetime: (Seconds)
Pressure: 0.015'' H2O

Data Sets

ID Instrument File  
2794 SMPS EPA2260B_SMPS.csv
2795 SMPS - SizeD EPA2260B_SizeD.csv
2796 NOx Box EPA2260B_NOx.csv
2797 Ozone Box EPA2260B_O3.csv
2798 TC EPA2260B_Temperature.csv

Data Set plots
Choose a file: Choose the X-Axis:

Experiment Set Details

Name: Weihua Li Experiments
Time format and units: Time format in timeline is the absolute local time.
Description:
Previous student experiments -- Weihua Li

Collaborators:

  • Weihua Li

Download

Download this Experiment (88.88 KB)

Contacts

Principal investigator:

David Cocker
E-mail: dcocker@engr.ucr.edu


Data Manager:

Chen Le
Phone: 9516603455
E-mail: cle030@ucr.edu

Reactants

Reactant Compound type Concentration Concentration units
NOx
  • NOx
 25 Parts Per Billion
SOA Surrogate 1.1 Parts Per Million
H2O2 1 Parts Per Million

20161009_EPA2260_TimeLine.csv Timeline

Time (America/Los_Angeles) Action
7:27 NO span starts; flow 2|20|off|35.0
7:39 NO 67.87; NOx 69.82; CO 15.87; GPT span starts; flow 2|20|0.7|35
7:44 NO 47.85; NOx 68.85; CO 15.87; O3 span starts; flow 2|20|0.7|off
7:59 O3 33.94; Starting E--W--Z sampling
8:20 Fill air off; Air Handlers on; Heaters on; Chiller #1 on
8:22 Inject NO 8.566 - 0.023 torr (253cc) into both bags
8:22 Inject NO2 5.172 - 0.023 torr (253cc) into both bags
8:23 Inject 100 uL PFH into both bags
8:24 Inect 66 uL liquid surrogate into both bags
8:26 Inject 15 uL acetaldehyde into both bags
8:32 Inject gas phase surrogate @500 to both bag bag for 4:42 min
8:44 Inject 400 uL H2O2 into both bag
9:04 Mix W-E bag for 8 mins
9:13 Close valve 14
10:14 Internally mix W bag for 1 min
10:16 Heaters off; Blacklights on; Elevators on
10:21 Elevator program deltaP = 0.018''
17:16 End of experiment

Citations
Cite this experiment:

Characterizations
Light Flux Characterizations:
(None)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
(None)

Chamber Details

Name: EPA chamber
Volume in cubic meters: 84.2
Shape: Rectangular Prism
Surface area in cubic meters: 126
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 2
Replacement date: 2017-11-07
Replacement frequency: As needed
Cleaning method: Flushing with air Flushing with air with UV lights on Oxidation Wipe with ultra-pure water if needed
o3 background: 10
nox background: 0
Particle background in micrograms per cubic meter: 0
Air filtration method: The chamber is using zero air from our air purification system
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 5
Temparature range (max degrees celcius): 45
Humidity Control: Yes
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 0.01
Relative humidity range (max percent): 80
Particle experiment capability: 1
Lights: Yes
Light source type(s): 350nm UVA Black Lamps
Supplemental information:
Additional Notes: