Experiment: UCR-CECERT-APL-Cocker Group_20161010_NOx/Diesel(Shell)/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2261A - Weihua

Experiment

Name: UCR-CECERT-APL-Cocker Group_20161010_NOx/Diesel(Shell)/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2261A - Weihua
Date: 2016-10-10

Organization
UCR-CECERT-APL-Cocker Group

Chamber
EPA chamber

Experiment Set
Weihua Li Experiments

Goals
Diesel photo-oxidation under NOx and SOA surrogate

Summary
1.1ppmc surrogate +50ppb NOx +150ul (shell) diesel+1ppmc H2O2 INSTRUMENTS: AMS, SMPS, GC1, HTDMA

Additional Notes
APM was down.

Experiment Details

Categories:

  • Photolysis, any phase
Temperature: 28
Relative Humidity: 0.01
Seeded Experiment: No
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 0.01
Reaction type:
Oxidant Name: Hydroxyl radical
Initial Oxidant Concentration Value: N/A (molecules_per_cubic_centimeter)
RO2 Main Fate: NO
RO2 Lifetime: (Seconds)
Pressure: 0.015'' H2O

Data Sets

ID Instrument File  
2799 SMPS EPA2261A_SMPS.csv
2800 Ozone Box EPA2261A_O3.csv
2801 NOx Box EPA2261A_NOx.csv
2802 SMPS - SizeD EPA2261A_SizeD.csv
2803 TC EPA2261A_Temperature.csv
2804 HTDMA EPA2261A_HTDMA.csv
2805 Licor EPA2261A_Licor.csv

Data Set plots
Choose a file: Choose the X-Axis:

Experiment Set Details

Name: Weihua Li Experiments
Time format and units: Time format in timeline is the absolute local time.
Description:
Previous student experiments -- Weihua Li

Collaborators:

  • Weihua Li

Download

Download this Experiment (106.47 KB)

Contacts

Principal investigator:

David Cocker
E-mail: dcocker@engr.ucr.edu


Data Manager:

Chen Le
Phone: 9516603455
E-mail: cle030@ucr.edu

Reactants

Reactant Compound type Concentration Concentration units
NOx
  • NOx
 50 Parts Per Billion
Diesel(Shell) 9999 Microgram Per Cubic Meter
SOA Surrogate 1.1 Parts Per Million
H2O2 1 Parts Per Million

20161010_EPA2261_TimeLine.csv Timeline

Time (America/Los_Angeles) Action
6:40 NO span starts; flow 2|20|35|off
6:55 NO 64.94; NOx 66.41; CO 15.33; GPT span starts; flow 2|20|35|0.7
7:10 NO 45.41; NOx 64.94; CO 15.28; O3 span starts; flow 2|20|0.7|off
7:20 Fill air off; Air Handlers on; Heaters on; Chiller #1 on
7:23 Inject NO 17.4 - 0.026 torr (253cc) into both bags
7:23 Inject NO2 10.301 - 0.022 torr (253cc) into both bags
7:23 Inject 100 uL PFH into both bags
7:25 O3 32.71; Starting E--W--Z sampling
7:25 Inject 66 uL liquid surrogate into both bags
7:26 Inject 15 uL acetaldehyde into both bags
7:33 Inject gas phase surrogate @500 to both bag for 4:42 min
7:45 Inject 400 uL H2O2 into both bag
8:05 Mix W-E bag for 8 mins
8:14 Close valve 14
8:15 Inject 150 uL diesel into W bag @40 V 60~70 C
9:15 Internally mix W bag for 1 min
9:17 Heaters off; Blacklights on; Elevators on
9:44 Elevator program deltaP=0.018
16:17 End of experiment

Citations
Cite this experiment:

Characterizations
Light Flux Characterizations:
(None)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
(None)

Chamber Details

Name: EPA chamber
Volume in cubic meters: 84.2
Shape: Rectangular Prism
Surface area in cubic meters: 126
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 2
Replacement date: 2017-11-07
Replacement frequency: As needed
Cleaning method: Flushing with air Flushing with air with UV lights on Oxidation Wipe with ultra-pure water if needed
o3 background: 10
nox background: 0
Particle background in micrograms per cubic meter: 0
Air filtration method: The chamber is using zero air from our air purification system
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 5
Temparature range (max degrees celcius): 45
Humidity Control: Yes
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 0.01
Relative humidity range (max percent): 80
Particle experiment capability: 1
Lights: Yes
Light source type(s): 350nm UVA Black Lamps
Supplemental information:
Additional Notes: