Experiment: UCR-CECERT-APL-Cocker Group_20161106_NOx/Summer Gasoline (Mobil 87)/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2273A - Weihua&Wenfu

Experiment

Name: UCR-CECERT-APL-Cocker Group_20161106_NOx/Summer Gasoline (Mobil 87)/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2273A - Weihua&Wenfu
Date: 2016-11-06

Organization
UCR-CECERT-APL-Cocker Group

Chamber
EPA chamber

Experiment Set
Weihua Li Experiments

Goals
Gasoline photo-oxidation under NOx and SOA surrogate

Summary
Target: 1.1ppmC SOA surrogate, 25ppb NOx, 500ul Gasoline(Both)+1ppmC H2O2(both) INSTRUMENTS: SMPS, GC1, AMS, VTDMA, HTDMA

Experiment Details

Categories:

  • Photolysis, any phase
Temperature: 28
Relative Humidity: 0.01
Seeded Experiment: No
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 0.01
Reaction type:
Oxidant Name: Hydroxyl radical
Initial Oxidant Concentration Value: N/A (molecules_per_cubic_centimeter)
RO2 Main Fate: NO
RO2 Lifetime: (Seconds)
Pressure: 0.015'' H2O

Data Sets

ID Instrument File  
2837 SMPS EPA2273A_SMPS.csv
2838 VTDMA EPA2273A_VTDMA.csv
2839 Ozone Box EPA2273A_O3.csv
2840 NOx Box EPA2273A_NOx.csv
2841 SMPS - SizeD EPA2273A_SizeD.csv
2842 TC EPA2273A_Temperature.csv
2843 HTDMA EPA2273A_HTDMA.csv
2844 Licor EPA2273A_Licor.csv

Data Set plots
Choose a file: Choose the X-Axis:

Experiment Set Details

Name: Weihua Li Experiments
Time format and units: Time format in timeline is the absolute local time.
Description:
Previous student experiments -- Weihua Li

Collaborators:

  • Weihua Li

Download

Download this Experiment (101.11 KB)

Contacts

Principal investigator:

David Cocker
E-mail: dcocker@engr.ucr.edu


Data Manager:

Chen Le
Phone: 9516603455
E-mail: cle030@ucr.edu

Reactants

Reactant Compound type Concentration Concentration units
NOx
  • NOx
 25 Parts Per Billion
Summer Gasoline (Mobil 87) 9999 Microgram Per Cubic Meter
SOA Surrogate 1.1 Parts Per Million
H2O2 1 Parts Per Million

20161106_EPA2273_TimeLine.csv Timeline

Time (America/Los_Angeles) Action
8:11 NO span starts; flow 2|20|off|35
8:26 NO 73.24; NOx 75.20; CO 16.65; GPT span starts; flow 2|20|0.7|35
8:43 NO 51.76; NOx 73.24; CO 16.46; O3 span starts; flow 2|20|0.7|off
8:44 Fill air off; Air Handlers on; Heaters on; Chiller #1 on
8:47 Inject 100 uL PFH into both bags
8:47 Inject NO 8.614 - 0.030 torr (253 cc) to both bags
8:47 Inject NO2 4.306 - 0.025 torr (253 cc) to both bags
8:50 Inject 77 uL liquid surrogate into both bags
8:57 Inject gas phase surrogate into both bags @ 500 cc/min for 4:42 mins
8:58 Inject 15 uL acetaldehyde into both bags
8:59 O3 34.91; Starting E--W--Z sampling
9:12 Inject 400 uL H2O2 into both bags
9:46 Inject 500 uL gasoline (Mobile 87) into W bag
10:20 Mix W-E bag for 8 mins
10:29 Close valve 14
10:30 Heaters off; Blacklights on
10:33 Elevators on (0.015'')
17:08 End of experiment

Citations
Cite this experiment:

Characterizations
Light Flux Characterizations:
(None)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
(None)

Chamber Details

Name: EPA chamber
Volume in cubic meters: 84.2
Shape: Rectangular Prism
Surface area in cubic meters: 126
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 2
Replacement date: 2017-11-07
Replacement frequency: As needed
Cleaning method: Flushing with air Flushing with air with UV lights on Oxidation Wipe with ultra-pure water if needed
o3 background: 10
nox background: 0
Particle background in micrograms per cubic meter: 0
Air filtration method: The chamber is using zero air from our air purification system
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 5
Temparature range (max degrees celcius): 45
Humidity Control: Yes
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 0.01
Relative humidity range (max percent): 80
Particle experiment capability: 1
Lights: Yes
Light source type(s): 350nm UVA Black Lamps
Supplemental information:
Additional Notes: