Experiment: UCR-CECERT-APL-Cocker Group_20161113_NOx/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2278B - Weihua
Experiment
Name: UCR-CECERT-APL-Cocker Group_20161113_NOx/SOA Surrogate/H2O2_Hydroxyl radical_No Seed_EPA2278B - Weihua
Date: 2016-11-13
Organization
UCR-CECERT-APL-Cocker Group
Chamber
EPA chamber
Experiment Set
Weihua Li Experiments
Goals
Gasoline photo-oxidation under NOx and SOA surrogate
Summary
Target: 1.1ppmC SOA surrogate, 25ppb NOx, 250ul Gasoline(A)+1ppmC H2O2(both) INSTRUMENTS: SMPS, GC1, AMS, VTDMAExperiment Details
Categories:
- Photolysis, any phase
- Blank/Control
Relative Humidity: 0.01
Seeded Experiment: No
Fuchs Adjusted Surface Area:
Condensation sink rate coefficient: 0.01
Reaction type:
Oxidant Name: Hydroxyl radical
Initial Oxidant Concentration Value: N/A (molecules_per_cubic_centimeter)
RO2 Main Fate: NO
RO2 Lifetime: (Seconds)
Pressure: 0.015'' H2O
Data Sets
ID | Instrument | File | |
---|---|---|---|
2906 | SMPS |
EPA2278B_SMPS.csv
|
|
2907 | NOx Box |
EPA2278B_NOx.csv
|
|
2908 | Ozone Box |
EPA2278B_O3.csv
|
|
2909 | SMPS - SizeD |
EPA2278B_SizeD.csv
|
|
2910 | TC |
EPA2278B_Temperature.csv
|
Data Set plots
Experiment Set Details
Name: Weihua Li Experiments
Time format and units: Time format in timeline is the absolute local time.
Description:
Previous student experiments -- Weihua Li
Collaborators:
- Weihua Li
Contacts
Principal investigator:
David Cocker
E-mail: dcocker@engr.ucr.edu
Data Manager:
Chen Le
Phone: 9516603455
E-mail: cle030@ucr.edu
Reactants
Reactant | Compound type | Concentration | Concentration units |
---|---|---|---|
NOx |
|
25 | Parts Per Billion |
SOA Surrogate | 1.1 | Parts Per Million | |
H2O2 | 1 | Parts Per Million |
20161113_EPA2278_TimeLine.csv
Timeline
Time (America/Los_Angeles) | Action |
6:46 | NO span starts; flow 2|20|off|35 |
7:01 | NO 65.92; NOx 66.89; CO 15.38; GPT span starts; flow 2|20|0.7|35 |
7:11 | Fill air off; Air Handlers on; Heaters on; Chiller #1 on |
7:11 | Inject 100 uL PFH into both bags |
7:13 | Inject NO 8.612 - 0.022 torr (253 cc) to both bags |
7:13 | Inject NO2 5.198 - 0.022 torr (253 cc) to both bags |
7:15 | Inject 66 uL liquid surrogate into both bags |
7:16 | Inject 15 uL acetaldehyde into both bags |
7:17 | NO 48.34; NOx 69.34; CO 15.38; O3 span starts; flow 2|20|0.7|off |
7:23 | Inject gas phase surrogate @ 500 cc/min into both bags for 4:42 mins |
7:23 | Inject 400 uL H2O2 into both bags |
7:32 | O3 32.96; Starting E--W--Z sampling |
7:55 | Mix W-E bag for 8 mins |
8:04 | Close valve 14 |
8:05 | Inject 250 uL gasoline (Arco 91) into W bag |
8:20 | Internally mix W bag for 1 min |
8:21 | Heaters off; Blacklights on |
8:30 | Elevators on (0.015'') |
15:28 | End of experiment |
Citations
Characterizations
(None)
Particle Loss Characterizations:
(None)
Vapor Loss Characterizations:
(None)
Chamber Details
Name: EPA chamber
Volume in cubic meters: 84.2
Shape: Rectangular Prism
Surface area in cubic meters: 126
Flow Mode: Batch
Flow through rate in liters per minute:
Body Material: Teflon
Body thickness: 2
Replacement date: 2017-11-07
Replacement frequency: As needed
Cleaning method:
Flushing with air
Flushing with air with UV lights on
Oxidation
Wipe with ultra-pure water if needed
o3 background: 10
nox background: 0
Particle background in micrograms per cubic meter: 0
Air filtration method: The chamber is using zero air from our air purification system
Mixing method: 0
Mixing method material:
Temparature Control: Yes
Temparature measurements recorded: Yes
Temparature range (min degrees celcius): 5
Temparature range (max degrees celcius): 45
Humidity Control: Yes
Humidity Measurements Recorded: Yes
Relative humidity range (min percent): 0.01
Relative humidity range (max percent): 80
Particle experiment capability: 1
Lights: Yes
Light source type(s):
350nm UVA Black Lamps
Supplemental information:
Additional Notes: