Particle Loss Characterization #13 - 2013-03-07

ID:
13

Name:
RHdry_22celsius_NearBag

Instrument:
Scanning Mobility Particle Sizer Particle Loss (#355)

Chamber:
Seinfeld chambers

Temperature (°C):
22

Relative humidity (%):
5

Particle composition:

  • Ammonium sulfate

Particle measurement size range:
17-952

Particle generation method:
Atomized from dilute solution of ammonium sulfate through a Nafion drier and Polonium 210 neutralizer

Date of characterization experiment:
2013-03-07

Months since calibration:

Wall loss experiment description:
Particles were introduced into the chamber at the desired concentration and left to decay at the studied environmental condition for several hours.

Wall loss rates calculation method:
The first-order rate coefficient (s-1) was calculated at each size bin by plotting the number concentration vs time trace of that size bin. Then the diameter vs. loss rate relationship was obtained and reported.

Frequency of particle loss experiments:
As needed

Wall loss correction description:
For a typical experiment, the time profile at each size bin is corrected for the loss rate at that size bin. There is an assumption that organic-coated aerosol behaves like ammonium sulfate. Generally, this correction technique is able to remove the loss trend of the aerosols during the experiment.

Link to supplemental information:
Crump, Flagan and Seinfeld, 1982: https://www.tandfonline.com/doi/pdf/10.1080/02786828308958636?needAccess=true

Additional notes:

Characterization data file:
Wallloss_Particle_RHdry_22celsius_NearBag_130307.csv


Experiments
ID Name Start date Experiment Category Reaction Type Reactant(s) Oxidant Name Temperature Humidity Type of Seed RO2 Main Fate Data Sets (count) Actions
390 2014 FIXCIT Study_20140117_4-hydroxy 3-peroxy ISOPOOH_Hydroxyl radical_No Seed_4,3-ISOPOOH + OH, low NO, dry, no seeds 2014-01-17 Gas phase chemical reaction Photooxidation 4-hydroxy 3-peroxy ISOPOOH Hydroxyl radical 25 5 HO2 14 Download
391 2014 FIXCIT Study_20140102_ISOPRENE/hydrogen peroxide_Hydroxyl radical_No Seed_Isoprene + OH, low NO, dry, no seeds 2014-01-02 Gas phase chemical reaction Photooxidation ISOPRENE, hydrogen peroxide Hydroxyl radical 27 5 HO2 10 Download
396 2014 FIXCIT Study_20140110_ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Alpha-pinene + OH, low NO, dry, (NH4)2SO4 seed at end 2014-01-10 Gas phase chemical reaction Photooxidation ALPHA-PINENE, hydrogen peroxide Hydroxyl radical 27 5 HO2 13 Download
397 2014 FIXCIT Study_20140114_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Isoprene + O3, low NO, dry, no seeds 2014-01-14 Gas phase chemical reaction Photooxidation ISOPRENE, CYCLOHEXANE Ozone 25 5 HO2 12 Download
400 2014 FIXCIT Study_20140125_METHACROLEIN/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate_Methacrolein + OH, low NO, dry, (NH4)2SO4 seed at end 2014-01-25 Gas phase chemical reaction, Aerosol formation Photooxidation METHACROLEIN, hydrogen peroxide Hydroxyl radical 28 5 Ammonium sulfate HO2 14 Download
405 2014 FIXCIT Study_20140121_ISOPRENE/hydrogen peroxide_Hydroxyl radical_No Seed_Isoprene + OH, low NO, dry, no seeds, lower initial concentration 2014-01-21 Gas phase chemical reaction Photooxidation ISOPRENE, hydrogen peroxide Hydroxyl radical 27 5 HO2 14 Download
408 2014 FIXCIT Study_20140127_trans-beta-IEPOX/methyl nitrite_Hydroxyl radical_No Seed_Trans-beta-IEPOX + OH, moderate NO, dry, no seeds 2014-01-27 Gas phase chemical reaction Photooxidation trans-beta-IEPOX, methyl nitrite Hydroxyl radical 25 5 NO 13 Download