Particle Loss Characterization #13 - 2013-03-07
ID:
13
Name:
RHdry_22celsius_NearBag
Instrument:
Scanning Mobility Particle Sizer Particle Loss (#355)
Chamber:
Seinfeld chambers
Temperature (°C):
22
Relative humidity (%):
5
Particle composition:
- Ammonium sulfate
Particle measurement size range:
17-952
Particle generation method:
Atomized from dilute solution of ammonium sulfate through a Nafion drier and Polonium 210 neutralizer
Date of characterization experiment:
2013-03-07
Months since calibration:
Wall loss experiment description:
Particles were introduced into the chamber at the desired concentration and left to decay at the studied environmental condition for several hours.
Wall loss rates calculation method:
The first-order rate coefficient (s-1) was calculated at each size bin by plotting the number concentration vs time trace of that size bin. Then the diameter vs. loss rate relationship was obtained and reported.
Frequency of particle loss experiments:
As needed
Wall loss correction description:
For a typical experiment, the time profile at each size bin is corrected for the loss rate at that size bin. There is an assumption that organic-coated aerosol behaves like ammonium sulfate. Generally, this correction technique is able to remove the loss trend of the aerosols during the experiment.
Link to supplemental information:
Crump, Flagan and Seinfeld, 1982: https://www.tandfonline.com/doi/pdf/10.1080/02786828308958636?needAccess=true
Additional notes:
Characterization data file:
Wallloss_Particle_RHdry_22celsius_NearBag_130307.csv
Experiments
ID | Name | Start date | Experiment Category | Reaction Type | Reactant(s) | Oxidant Name | Temperature | Humidity | Type of Seed | RO2 Main Fate | Data Sets (count) | Actions |
---|---|---|---|---|---|---|---|---|---|---|---|---|
390 | 2014 FIXCIT Study_20140117_4-hydroxy 3-peroxy ISOPOOH_Hydroxyl radical_No Seed_4,3-ISOPOOH + OH, low NO, dry, no seeds | 2014-01-17 | Gas phase chemical reaction | Photooxidation | 4-hydroxy 3-peroxy ISOPOOH | Hydroxyl radical | 25 | 5 | HO2 | 14 | Download | |
391 | 2014 FIXCIT Study_20140102_ISOPRENE/hydrogen peroxide_Hydroxyl radical_No Seed_Isoprene + OH, low NO, dry, no seeds | 2014-01-02 | Gas phase chemical reaction | Photooxidation | ISOPRENE, hydrogen peroxide | Hydroxyl radical | 27 | 5 | HO2 | 10 | Download | |
396 | 2014 FIXCIT Study_20140110_ALPHA-PINENE/hydrogen peroxide_Hydroxyl radical_No Seed_Alpha-pinene + OH, low NO, dry, (NH4)2SO4 seed at end | 2014-01-10 | Gas phase chemical reaction | Photooxidation | ALPHA-PINENE, hydrogen peroxide | Hydroxyl radical | 27 | 5 | HO2 | 13 | Download | |
397 | 2014 FIXCIT Study_20140114_ISOPRENE/CYCLOHEXANE_Ozone_No Seed_Isoprene + O3, low NO, dry, no seeds | 2014-01-14 | Gas phase chemical reaction | Photooxidation | ISOPRENE, CYCLOHEXANE | Ozone | 25 | 5 | HO2 | 12 | Download | |
400 | 2014 FIXCIT Study_20140125_METHACROLEIN/hydrogen peroxide_Hydroxyl radical_Ammonium sulfate_Methacrolein + OH, low NO, dry, (NH4)2SO4 seed at end | 2014-01-25 | Gas phase chemical reaction, Aerosol formation | Photooxidation | METHACROLEIN, hydrogen peroxide | Hydroxyl radical | 28 | 5 | Ammonium sulfate | HO2 | 14 | Download |
405 | 2014 FIXCIT Study_20140121_ISOPRENE/hydrogen peroxide_Hydroxyl radical_No Seed_Isoprene + OH, low NO, dry, no seeds, lower initial concentration | 2014-01-21 | Gas phase chemical reaction | Photooxidation | ISOPRENE, hydrogen peroxide | Hydroxyl radical | 27 | 5 | HO2 | 14 | Download | |
408 | 2014 FIXCIT Study_20140127_trans-beta-IEPOX/methyl nitrite_Hydroxyl radical_No Seed_Trans-beta-IEPOX + OH, moderate NO, dry, no seeds | 2014-01-27 | Gas phase chemical reaction | Photooxidation | trans-beta-IEPOX, methyl nitrite | Hydroxyl radical | 25 | 5 | NO | 13 | Download |