Vapor Loss Characterization #12 - General Jimenez Chambers Vapor Wall Loss Characterization
Name:
General Jimenez Chambers Vapor Wall Loss Characterization
Instrument:
Nitrate-adduct Chemical Ionization Mass Spectrometer
Chamber:
1-White (1W)
Temperature (°C):
20
Relative humidity (%):
0
Volatile compound name or class:
3. Multifunctional compounds generated in-situ.
Volatile compound source:
- In-situ formation via reaction
Date of characterization experiment:
2021-11-05
Months since calibration:
0
Wall loss experiment description:
Compounds generated in-situ are produced through a 10 second photo-oxidation of commercially available precursors (1-alkanols), where photo-oxidation start and stop times are precisely controlled by photolysis of CH3ONO (methyl nitrite) in the presence of NO (nitric oxide) using 350 nm blacklights. Lower volatility, multifunctional compounds that are generated are monitored in real time by a NO3- CIMS at 1Hz. No fan should be used after lights turned on/off and the chamber is particle and should produce little aerosol during the oxidation.
Vapor loss calculation method:
The time series of the compounds are fitted and modeled using a kinetic solver (KinSim) which runs within Igor Pro. The production, transfer to chamber walls and evaporation from walls are modeled.
Parameterization developed:
Yes
Parameterization description:
A first order rate of transfer from gas-phase to the chamber walls is calculated for the chamber and a compound-dependent saturation vapor concentration (C*) is computed.
Link to supplemental information:
Detailed descriptions of the method and applications and paramaterizations for the Jimenez Group chambers are contained in the following references:
https://pubs.acs.org/doi/abs/10.1021/acs.est.6b00606,
https://pubs.acs.org/doi/abs/10.1021/acs.est.7b02144,
https://www.nature.com/articles/s42004-019-0200-x
Additional notes:
See also the ICARUS vapor wall loss protocol. Method 2 and the data analysis method (Part 3) are applicable to the method described here.
Characterization data file:
Jimenez_CUBoulder_GeneralVaporWallLoss_Characterization.csv
Experiments
| ID | Name | Start date | Experiment Category | Reaction Type | Reactant(s) | Oxidant Name | Temperature | Humidity | Type of Seed | RO2 Main Fate | Data Sets (count) | Actions |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 100 | Jimenez Lab_20170109_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_120_ug/m3_#8 | 2017-01-09 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 23 | 0 | Di-octyl sebacate | NO | 3 | Download |
| 153 | Jimenez Lab_20160823_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_2.9_ug/m3_#1 | 2016-08-23 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 27.7 | 0 | Di-octyl sebacate | NO | 3 | Download |
| 154 | Jimenez Lab_20160818_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_4.5_ug/m3_#2 | 2016-08-18 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 28 | 0 | Di-octyl sebacate | NO | 3 | Download |
| 155 | Jimenez Lab_20170108_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_5.8_ug/m3_DOS_#3 | 2017-01-08 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 25 | 0 | Di-octyl sebacate | NO | 3 | Download |
| 156 | Jimenez Lab_20160828_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_11_ug/m3_DOS_#4 | 2016-08-28 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 23.3 | 0 | Di-octyl sebacate | NO | 4 | Download |
| 157 | Jimenez Lab_20160827_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_13_ug/m3_#5 | 2016-08-27 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 25.1 | 0.2 | Di-octyl sebacate | NO | 4 | Download |
| 158 | Jimenez Lab_20160815_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_23_ug/m3_#6 | 2016-08-15 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 27 | 0.2 | Di-octyl sebacate | NO | 3 | Download |
| 159 | Jimenez Lab_20170107_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_80_ug/m3_#7 | 2017-01-07 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 25 | 0 | Di-octyl sebacate | NO | 3 | Download |
| 160 | Jimenez Lab_20160822_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/1-DODECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Di-octyl sebacate_140_ug/m3_#9 | 2016-08-22 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, 1-DODECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 27 | 0.3 | Di-octyl sebacate | NO | 3 | Download |
| 237 | Jimenez Lab_20170330_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_30.2_ug/m3_AS6 | 2017-03-30 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | 45 | Ammonium sulfate | NO | 3 | Download |
| 243 | Jimenez Lab_20160726_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_Ammonium sulfate_44.3_ug/m3_AS1 | 2016-07-26 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 25 | <1 | Ammonium sulfate | NO | 4 | Download |
| 244 | Jimenez Lab_20160816_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_6.20_ug/m3_AS2 | 2016-08-16 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Ammonium sulfate | NO | 3 | Download |
| 245 | Jimenez Lab_20160816_1-octanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_18.6_ug/m3_AS3 | 2016-08-16 | Volatility and partitioning | Photooxidation | 1-octanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Ammonium sulfate | NO | 5 | Download |
| 246 | Jimenez Lab_20180328_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_9.4_ug/m3_AS4 | 2018-03-28 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Ammonium sulfate | NO | 3 | Download |
| 247 | Jimenez Lab_20170329_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_12.5_ug/m3_AS5 | 2017-03-29 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | 46 | Ammonium sulfate | NO | 3 | Download |
| 248 | Jimenez Lab_20180725_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Ammonium sulfate_14.1_ug/m3_AS7 | 2018-07-25 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | 46 | Ammonium sulfate | NO | 5 | Download |
| 249 | Jimenez Lab_20170316_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_alpha pinene_107.4_ug/m3_aP1 | 2017-03-16 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | alpha pinene | NO | 3 | Download |
| 250 | Jimenez Lab_20171106_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_alpha pinene_15.0_ug/m3_aP2 | 2017-11-06 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | alpha pinene | NO | 5 | Download |
| 251 | Jimenez Lab_20180313_1-DECANOL/Methyl nitrite/nitric oxide_Hydroxyl radical_DOS_415.6_ug/m3_DOS1 | 2018-03-13 | Volatility and partitioning | Photooxidation | 1-DECANOL, Methyl nitrite, nitric oxide | Hydroxyl radical | 25 | <1 | DOS | NO | 3 | Download |
| 252 | Jimenez Lab_20170125_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Oleic Acid_15.6_ug/m3_OA1 | 2017-01-25 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Oleic Acid | NO | 3 | Download |
| 260 | Jimenez Lab_20170126_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Oleic Acid_2.9_ug/m3_OA2 | 2017-01-26 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Oleic Acid | NO | 3 | Download |
| 261 | Jimenez Lab_20170127_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Oleic Acid_1.75_ug/m3_OA3 | 2017-01-27 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Oleic Acid | NO | 3 | Download |
| 262 | Jimenez Lab_20171010_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Pentaethylene Glycol_4.0_ug/m3_PEG1 | 2017-10-10 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Pentaethylene Glycol | NO | 5 | Download |
| 263 | Jimenez Lab_20171018_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Pentaethylene Glycol_7.85_ug/m3_PEG2 | 2017-10-18 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Pentaethylene Glycol | NO | 7 | Download |
| 264 | Jimenez Lab_20180307_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Pentaethylene Glycol_4.5_ug/m3_PEG3 | 2018-03-07 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Pentaethylene Glycol | NO | 4 | Download |
| 265 | Jimenez Lab_20170331_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Squalane_26.6_ug/m3_Sq1 | 2017-03-31 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Squalane | NO | 3 | Download |
| 266 | Jimenez Lab_20171103_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Squalane_10.8_ug/m3_Sq2 | 2017-11-03 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Squalane | NO | 5 | Download |
| 267 | Jimenez Lab_20170320_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Sucrose_32.1_ug/m3_Su1 | 2017-03-20 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Sucrose | NO | 3 | Download |
| 268 | Jimenez Lab_20170321_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Sucrose_10.4_ug/m3_Su2 | 2017-03-21 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Sucrose | NO | 3 | Download |
| 269 | Jimenez Lab_20180504_1-Hexanol/1-octanol/1-Nonanol/1-DECANOL/Methyl nitrite/nitric oxide/1-DODECANOL_Hydroxyl radical_Sucrose_21.6_ug/m3_clone_Su3 | 2018-05-04 | Volatility and partitioning | Photooxidation | 1-Hexanol, 1-octanol, 1-Nonanol, 1-DECANOL, Methyl nitrite, nitric oxide, 1-DODECANOL | Hydroxyl radical | 25 | <1 | Sucrose | NO | 3 | Download |
| 658 | Jimenez Lab_20181121_Toluene/Methyl nitrite/Nitric oxide_Hydroxyl radical_Ammonium sulfate | 2018-11-21 | Volatility and partitioning | Photooxidation | Toluene, Methyl nitrite, Nitric oxide | Hydroxyl radical | 25 | 0 | Ammonium sulfate | NO | 4 | Download |